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Otto Stern(1888-1969): Pioneer of molecular beam research
OTTO STERN was born on February 17, 1888 in Upper Silesia,
Germany, in a prosperous Jewish family of merchants. The parents
encouraged their children (two sons and three daughters) to
satisfy the thirst for knowledge without setting their sights on
career goals.
He attended the Johannes Gymnasium and graduated in 1906. The
course emphasised classics at the expense of mathematics and the
sciences. Bu he supplemented his education by private readings of
the various books that his father put at his disposal.
Stern continued his studies at the Universities of Freiburg,
Munich and Breslau, migrating from one university to another. So
this academic tradition enabled him to attend lectures on a
variety of subjects, without regard to curricula or to the time
needed for completion of the course requirements. Thus Stern
attended lectures on theoretical physics by the legendary Arnold
Sommerfeld and on experimental physics (blackbody radiation) by
Otto Lummer and Ernst Prinysheim.
The books of Boltzmann on molecular theory and statistical
mechanics by Clausius and Nernst on thermodynamics seemed to have
influenced his choice of his line of research.
Returning to Breslau to complete his university degree, he
decided to major in physical chemistry because of the influence
of two particular professors in the department. His doctoral
thesis (1912) was both theoretical and experimental and set the
style for his future research. He was indeed an ``experimenting
theoretician''. His scientific work can be grouped under two
district categories: Theoretical Work (1912-1918).
Immediately after taking his doctorate, he joined Albert Einstein
in 1912 as a postdoctoral fellow in Prague, moving with him to
Zurich in 1913; with Ehrenfest and Max von Lane whom he came to
know in Zurich. The status of Privatdozent (lecturer without
salary) - which carried prestige, that he achieved in the Federal
Institute of Technology, Zurich was transferred by him to the
University of Frankfurt in 1914. During 1914-18, he served as a
technical officer in the German army. He considered this period
as important not only for the publication of some scientific
papers but a certain attitude he developed towards the selection
of research problems.
Stern was stationed in a small village during 1916 as a military
weather observer where the duties of a routine nature left him
plenty of free time which he did not waste: he took up the
tedious problem of calculating the energy of a system of coupled
mass points, performing the computations in longhand.
Stern was more attracted to Einstein by his work in molecular
theory than his famous theory of relativity. He applied the
quantum concepts to explain the curious temperature behaviour of
the specific heat of crystalline substances.
Stern acknowledged what he really learned from Einstein planted
the seed for the major accomplishments of his later career (Nobel
Laureate). What he really learned from Einstein was essential
scientific traits: how to evaluate the importance of current
physical problems which questions to ask and what experiments
should be undertaken at a given time.
An ingenious solution
The second major work dealt with various problems in statistical
thermodynamics, in particular the entropy of a monatomic gas. The
expression for entropy contains an arbitrary constant that cannot
be computed but that greatly affects such properties as the
vapour press of a solid or the chemical equilibrium of reacting
gases.
The method for applying quantum concepts to a perfect gas had not
yet been discovered. Stem gave an ingenious solution to avoid the
need to apply quantum theory to a gas. He instead considered the
equilibrium of a solid crystal with its vapour at a high
temperature. This satisfies the conditions to use statistical
mechanics for the gas and to apply quantum concepts only to the
solid. He then applied Einstein's theory for specific that and
the third law of thermo dynamics developed by Nerrst and derived
successfully the result.
Towards the end of World War I, many German scientists were
placed at Nernst's laboratory, University of Berlin, for
conducting military research. Here Stern met two excellent
experimentalists James Franck and Max Volmar: it is probable that
his change-over from theoretical to experimental work was the
result of their influence.
Experimental work (1919-45)
On returning to Frankfurt, Stern began to work with Max Born,
director of the Institute for Theoretical Physics. He began to
work on some theoretical problems but felt it was necessary to
provide experimental proof for the fundamental concepts used in
molecular theory. So he began to develop the molecular-beam
method.
Stern picked up the work done by Dunoyer in 1911 for
investigating the properties of free atoms, which had been lying
unnoticed. Stern applied this technique, using beams of silver
atoms and confirmed the theoretical values earlier obtained (in
1850), within the limits of experimental error. Einstein's
teaching, how to recognise the important problems, is evident
here.
Not particularly skilled in handling experimental technique for
carrying out the experiment he had designed, Stern sought the
assistance of his colleague Walther Gerlach. Together they
succeeded in 1920 in proving the reality of space quantization
and in measuring the magnetic moment of the silver atom. The five
papers dealing with the Stern-Gerlach experiment received wide
attention and secured for Stern a place of honour in the history
of physics.
In 1921, Stern joined as professor of theoretical physics at the
University of Rostock. After two years, he received an invitation
from the University of Hamburg. On 1 January 1923 he joined as
professor of physical chemistry and set out to organize a
laboratory for molecular-beam research and to devise a program
for conducting this research. This program yielded significant
results: developing new and improved techniques, demonstrating
the wave nature of a particle, the assumption introduced by de
Broglie (1924); measuring the magnetic moment of proton. These
experiments were essential for the acceptance of new ideas that
eventually laid the foundation of modern physics.
With the advent of the Nazi regime (1933), the momentum of the
Hamburg laboratory came to a sudden halt. Stern's colleagues of
Jewish origin were dismissed; in protest Stern resigned,
foreseeing for himself a similar fate.
Stern migrated to the U.S. and took up the post as research
professor in the Carnegie Institute of Technology. Though a
number of significant papers issued from Carnegie, the work did
not progress rapidly, as the funds during the depression years
were meager. He retired in 1946 and settled in Berkley,
California. Though he maintained local contacts with physicists,
he shunned public appearances. He died on August 17, 1969 at the
age of 81.
Stern received several honours: honorary doctorates from the
University of California and ETH in Zarich; member of the
National Academy of Sciences (1945) and the American
Philosophical Society; Noble Prize in Physics (1943)(The
dixtionary of scientific biography vol XIII)
R.Parthasarathy
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